To obtain reliable measurements of the environmental radionuclide activity using HPGe (High Purity Germanium) detectors, the knowledge of the absolute peak efficiency is required. This work presents a practical procedure for efficiency calibration of a coaxial n-type and a well-type HPGe detector using experimental and Monte Carlo simulations methods. The method was performed in an energy range from 40 to 1460 keV and it can be used for both, solid and liquid environmental samples. The calibration was initially verified measuring several reference materials provided by the IAEA (International Atomic Energy Agency). Finally, through the participation in two Proficiency Tests organized by IAEA for the members of the ALMERA network (Analytical Laboratories for the Measurement of Environmental Radioactivity) the validity of the developed procedure was confirmed. The validation also showed that measurement of 226Ra should be conducted using coaxial n-type HPGe detector in order to minimize the true coincidence summing effect.